Общее описание фосфора как элемента V группы, металла. Характеристика его основных аллотропных модификаций. Применение треххлористого и пятихлористого фосфора при синтезах различных органических веществ. Источники загрязнения окружающей среды фосфором.
Change of palladium ions concentration during cementation on the magnesium disk in dimethylformamide solution. Chemical microparticles and agglomerates anorganic chlorine compound. Palladium adhesion to the substrate surface in dimethylformamide.
The desorption non-isothermal kinetics of preliminary adsorbed Cl, Br, and I-containing volatile halocarbons from the surface of surrogates for atmospheric solid aerosols (fumed silica and alumina, silica gel and H-mordenite) was studied by TPD MS.
Schematisation of defects in oil pipelines. Numerical and analytical methods of calculating stress. Paris power dependence. Methods of definition of cyclic crack resistance of a pipe material. Characteristics of cyclic crack resistance of steel.
A new universal method of estimating the chemical shifts values of the methylene groups. Change the values of 1H and 13C each methylene group in the result of the conversion by replacing the long fragments –(CH2)K– and –(CH2)I– of the Vice alculated.
This work analyzes ternary phase diagrams of magnesium with two rare-earth metals of different subgroups, conducted in IMET RAS in connection with the development of high-temperature magnesium alloys. A lot number of phase diagrams were discovered.
Study of swelling kinetics as compared to solvents of various nature (water in various pH, ethanol, toluene) was carried out. IR comparative spectra were obtained for different composites. High anti-bacterial action of the synthesized nanocomposites.
Analysis of spectral characteristics of a steady state (excitation and emission) spectra of photoluminescence of europium included in the single crystal and glassy lithium tetraborate and silica to distinguish oxidation, the site-symmetry and morphology.
Technique of chemical etching as a promising method for creating nanostructures of si. The development of photovoltaic converters and methods of production resoursesaving for silicon micro - and nanostructures based on isotropic and anisotropic etching.
- 220. Phylogenetic study on structural elements of HIV-1 poly(A) region. 2. USE domain and TAR hairpin
Phylogenetic study of the structural elements of poly(a) region of human immunodeficiency virus type 1 (HIV-1) to stimulate polyadenylation HIV-1 transcription and TRANS-activation response hairpin that combines space and uses the AAUAAA signals.
Homogeneous precipitation synthesis of nanocomposites - activated carbon – zirconium(IV) oxide. Characterization of samples by x-ray diffraction analysis and electron microscopy. Sorption properties and the degree of extraction of phosphate ions.
Physico-chemical characteristics of I-40 and MS-20 commercial mineral oils. The use of such oils for the lubrication of molds in the manufacture of glass containers. The study of the thermal stability of oils and their fractions of hydrocarbons.
The use of block copolymers on the basis of oxides of ethylene and propylene as demulsifiers of oil emulsions. Determination of the dependence of their physico-chemical properties from the content oxyethylene and oxypropylene groups in the molecule.
Describes macroscopic of piezoelectric response of a macroscopic array of nanorod crystals of cadmium sulfide. Research of irregular shape of six-sided polyhedron and demonstrate piezoelectric response similar to their counterpart crystals grown.
Proving that MBT fine fraction is fit-to-use as functional material for methane degradation layer. Confirmation of the methane degradation efficiency in fine MBT fraction is important from the ecological point of view. The use of a fine fraction.
The role of the technique of volumetric titration with a working solution of sodium thiosulfate with a visual indication of the starch equivalence point during the analysis of the residual active chlorine. Evaluation of its advantages and disadvantages.
Hierarchical structure and multi-level organization of cellulose. Preparation of cellulosic nanomaterials. Mechanically-induced deconstructing strategy. Cellulose properties (mechanical, thermal, and barrier) that change during nanoscaling process.
- 228. Preparation and properties of hybrid poly(3,4-ethylenedioxythiophene)–carbon nanotubes composites
It was investigated the infrared spectra of the hybrid composites poly. The current-voltage characteristics of the obtained materials. It is shown that increasing the content of carbon nanotubes leads to decrease of the resistance of hybrid films.
Research transparent conducting n-type semiconductor zinc oxide films, which have been extensively studied in recent year because they exhibit wide band gap. Analysis of scanning electron microscopy which used for study of surface morphological changes.
The use of ethylene oxide (EO) as a chemical intermediate. A suggested process flow diagram Ethylene Oxide Process. Process Details: feed, effluent, recycle streams, deliverables and grading. Economic analysis the equivalent annual operating cost.
Synthesis of sorption-active material carrying groups 5% chlorosulfonic acid by radiation-induced graft polymerization of styrene monomer on the surface of non-woven polypropylene fabric with subsequent sulfonation of the grafted polystyrene chains.
Production and use of non-isocyanate polyurethanes based on cyclic carbonate oligomers. A suitable non-isocyanate polyurethane and a hybrid polymer comprising other different oligomeric systems. Pollution of unstable biuret and allophanate units.
Determine the optimal parameters of synthesis and base properties of nano-tubular crystals Mg-Ni chrysotiles. temperature ranges and pressure for the synthesis of nano-tubular crystals all synthesed chrysotile at the time of isothermal exposure.
Применение Pt, Ru и Pt-Ru катализаторов в реакции дегидрирования, селективного каталитического окисления метана и парокислородной конверсии СН4. Возможные изменения конверсии СН4 в реакциях СКО, парокислородной конверсии и термическом разложении СН4.
By Reaction with Alkyl Halides. Nucleophilic Addition. Oxidation of Ring Carbon Atoms Followed by Addition. Reduction of Exocyclic Double Bonds. Ring Cleavage Reactions. Coupling of Pyrazol-3-ones with Aryl Diazonium Salts. Oxidative Coupling, silylation.
Проведення розрахунку квантово-хімічних дескрипторів 9 похідних піридинкарбонових кислот методом АМ1. Описання залежності між електронно-просторовою структурою досліджуваних сполук і їх протитуберкульозною активністю з використанням QSAR-моделей.
Combination of methods quantum chemistry. Geometrical and electronic structure of clinoptilolite clusters modified by zinc and calcium. Redistribution of electronic density on the oxygen atoms of clusters during formation of bonds with zinc and calcium.
Physical and chemical properties of the drugs. Reactions to chloride ions Cl- in a solution of AgNO3 in HNO3. Photocolorimetry with painted ferum hydroxamate. Reaction on heterocyclic atom of nitrogen. Using of methods of quantitative determination.
SiO2 materials containing different magnetic fillers are obtained by the sol-gel method. It is studied the weakening of electromagnetic radiation in the frequency range 8–11.5 GHz by the materials obtained with the use of panoramic attenuation measurers.
- 240. Reactions of 1-(4-hydroxyphenyl)-3-(4-nitrophenyl)-5-ethyl-1,2,4-triazole with electrophilic agents
To synthesize new biologically active compounds, the reactions of electrophilic substitution of 1-(4-hydroxyphenyl)-3-(4-nitrophenyl)-5-ethyl-1, 2, 4-triazole (I) have been studied. The structure of the new compounds was confirmed by 1H NMR spectra.